The interplay between spin densities and magnetic superexchange interactions: Case studies of monoand trinuclear bis(oxamato)-type complexes

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Date
2017
Volume
8
Issue
1
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Publisher
Frankfurt am Main : Beilstein-Institut zur Förderung der Chemischen Wissenschaften
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Abstract

For future molecular spintronic applications the possibility to modify and tailor the magnetic properties of transition-metal complexes is very promising. One of such possibilities is given by the countless derivatization offered by carbon chemistry. They allow for altering chemical structures and, in doing so, to tune magnetic properties of molecular spin-carrying compounds. With emphasis on the interplay of the spin density distribution of mononuclear and magnetic superexchange couplings of trinuclear bis(oxamato)- type complexes we review on efforts on such magneto-structural correlations.

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Keywords
Bis(oxamato), Bis(oxamidato), Copper(II), Electron nuclear double resonance, Electron paramagnetic resonance, Magnetic superexchange interactions, Pulsed electron-electron double resonance, Spin density distribution, Carbon, Chemical compounds, Electrons, Magnetic properties, Magnetic resonance, Magnetism, Metal complexes, Paramagnetic resonance, Resonance, Transition metal compounds, Transition metals, Carbon chemistry, Electron nuclear double resonance, Magnetostructural correlations, Pulsed electron-electron double resonances, Spin density distributions, Spintronic applications, Super-exchange coupling, Superexchange interaction, Magnetic couplings
Citation
Aliabadi, A., Büchner, B., Kataev, V., & Rüffer, T. (2017). The interplay between spin densities and magnetic superexchange interactions: Case studies of monoand trinuclear bis(oxamato)-type complexes. 8(1). https://doi.org//10.3762/bjnano.8.224
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CC BY 4.0 Unported