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Pfeiffer et al 1999, Coherent Motion of Low Frequency Vibrations.pdf | 196,88 kB | Adobe PDF | View/Open |
Title: | Coherent motion of low frequency vibrations in ultrafast excited state proton transfer |
Authors: | Pfeiffer, M.; Chudoba, C.; Lau, A.; Lenz, K.; Elsaesser, T. |
Publishers version: | https://doi.org/10.1155/1999/23283 |
URI: | https://doi.org/10.34657/4033 https://oa.tib.eu/renate/handle/123456789/5404 |
Issue Date: | 1999 |
Published in: | Laser Chemistry 19 (1999), Nr. 1-4 |
Journal: | Laser Chemistry |
Volume: | 19 |
Issue: | 1-4 |
Page Start: | 101 |
Publisher: | Routledge : Taylor and Francis Inc. |
Abstract: | Photoexcitation of internal proton transfer in the tinuvin molecule causes the excitation of some low frequency vibrational modes which oscillate with high amplitudes in a coherent manner over 700 fs. Such effect is observed for the first time applying two color pump/probe measurement with 25 fs pulses. Based on resonance Raman spectra a normal coordinate analysis of the modes is performed. It is shown that the nuclear movement given by the normal vibration of one of the modes serves to open up a barrierfree proton transfer path. |
Keywords: | Excited state-molecules; Potential energy surface; Proton transfer; Raman spectra-molecules; Ultrafast time resolved spectra |
Type: | article; Text |
Publishing status: | publishedVersion |
DDC: | 530 |
License: | CC BY 3.0 Unported |
Link to license: | https://creativecommons.org/licenses/by/3.0/ |
Appears in Collections: | Physik |
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Pfeiffer, M., C. Chudoba, A. Lau, K. Lenz and T. Elsaesser, 1999. Coherent motion of low frequency vibrations in ultrafast excited state proton transfer. 1999. Routledge : Taylor and Francis Inc.
Pfeiffer, M., Chudoba, C., Lau, A., Lenz, K. and Elsaesser, T. (1999) “Coherent motion of low frequency vibrations in ultrafast excited state proton transfer.” Routledge : Taylor and Francis Inc. doi: https://doi.org/10.1155/1999/23283.
Pfeiffer M, Chudoba C, Lau A, Lenz K, Elsaesser T. Coherent motion of low frequency vibrations in ultrafast excited state proton transfer. Vol. 19. Routledge : Taylor and Francis Inc.; 1999.
Pfeiffer, M., Chudoba, C., Lau, A., Lenz, K., & Elsaesser, T. (1999). Coherent motion of low frequency vibrations in ultrafast excited state proton transfer (Version publishedVersion, Vol. 19). Version publishedVersion, Vol. 19. Routledge : Taylor and Francis Inc. https://doi.org/https://doi.org/10.1155/1999/23283
Pfeiffer M, Chudoba C, Lau A, Lenz K, Elsaesser T. Coherent motion of low frequency vibrations in ultrafast excited state proton transfer. 1999;19(1-4). doi:https://doi.org/10.1155/1999/23283
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