[2,2-Bis(diphenylphosphanyl)propane κ2P,P0] tetracarbonylchromium(0)dichloromethane monosolvate
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Date
Volume
66
Issue
11
Journal
Acta Crystallographica Section E: Structure Reports Online
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Publisher
Chester : International Union of Crystallography
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Abstract
The title compound, [Cr(C27H26P2)(CO) 4]·CH2Cl2, was obtained by the reaction of Ph2PCMe2PPh2 with Cr(CO)6 in refluxing toluene by substitution of two carbonyl ligands. The CrC 4P2 coordination geometry at the Cr atom is distorted octa-hedral, with a P - Cr - P bite angle of 70.27 (2)°.
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CC BY 4.0 Unported