Polymeric monolithic materials: Syntheses, properties, functionalization and applications
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Volume
48
Issue
8
Journal
Polymer
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Amsterdam : Elsevier
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Abstract
The synthetic particularities for the synthesis of polymer-based monolithic materials are summarized. In this context, monoliths prepared via thermal-, UV- or electron-beam triggered free radical polymerization, controlled TEMPO-mediated radical polymerization, polyaddition, polycondensation as well as living ring-opening metathesis polymerization (ROMP) will be covered. Particular attention is devoted to the aspects of controlling pore sizes, pore volumes and pore size distributions as well as functionalization of these supports. Finally, selected, recent applications in separation science, (bio-) catalysis and chip technology will be summarized. © 2007 Elsevier Ltd. All rights reserved.
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Keywords
Monolithic materials, Polymer materials, Polymer synthesis, Catalysis, Electron beams, Free radical polymerization, Polycondensation, Pore size, Synthesis (chemical), Monolithic materials, Polymer materials, Polymer synthesis, Biopolymers, catalyst, condensation polymer, polymer property, polymerization, pore size, synthesis
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Article
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CC BY-NC-ND 3.0 Unported