{N,N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl]methylamine- κ2 P,P′}bis(η5-cyclopentadienyl) titanium(II)
Date
2013
Volume
69
Issue
6
Journal
Series Titel
Book Title
Publisher
Chester : International Union of Crystallography
Link to publishers version
Abstract
The title compound, [Ti(C5H5)2(C 9H11F12NO4P2)], is a four-membered titanacycle obtained from the reaction of Cp2Ti(η 2-Me3SiC2SiMe3) and CH 3N[P(OCH2CF3)2]2 {N,N-bis[bis(trifluoroethoxy)phosphanyl]methylamine, tfepma}. The Ti II atom is coordinated by two cyclopentadienyl (Cp) ligands and the chelating tfepma ligand in a strongly distorted tetrahedral geometry. The molecule is located on a mirror plane.
Description
Keywords
chemistry, crystal structures
Citation
Haehnel, M., Hansen, S., Spannenberg, A., & Beweries, T. (2013). {N,N-Bis[bis(2,2,2-trifluoroethoxy)phosphanyl]methylamine- κ2 P,P′}bis(η5-cyclopentadienyl) titanium(II). 69(6). https://doi.org//10.1107/S1600536813014244
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License
CC BY 4.0 Unported