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Title: Carbonyl{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(4,4, 5,5-tetramethyl-1,3,2-dioxaphospholan-2-yl)oxy]biphenyl-κ2 P,P′}hydrido(triphenylphosphane-κP)rhodium(I) diethyl ether trisolvate
Authors: Selent, D.Spannenberg, A.Börner, A.
Publishers version: https://doi.org/10.1107/S1600536812049124
URI: https://doi.org/10.34657/4202
https://oa.tib.eu/renate/handle/123456789/5573
Issue Date: 2013
Published in: Acta Crystallographica Section E: Structure Reports Online 69 (2013), 1
Publisher: Chester : International Union of Crystallography
Abstract: In the title compound, [RhH(C74H68O8P2)(C18H15P)(CO)]·3C4H10O, the CHP3 coordination set at the RhI ion is arranged in a distorted trigonal-bipyramidal geometry with the P atoms adopting equatorial coordination sites and the C atom of the carbonyl ligand as well as the H atom adopting the axial sites. The asymmetric unit contains two very similar molecules of the rhodium complex, two half-occupied diethyl ether molecules and further diethyl ether solvent molecules which could not be modelled successfully. Therefore contributions of the latter were removed from the diffraction data using the SQUEEZE procedure in PLATON [Spek (2009). Acta Cryst. D65, 148-155].
Keywords: chemistry; crystal structures
Type: article; Text
Publishing status: publishedVersion
DDC: 540
License: CC BY 4.0 Unported
Link to license: https://creativecommons.org/licenses/by/4.0/
Appears in Collections:Chemie

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Selent, D., A. Spannenberg and A. Börner, 2013. Carbonyl{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(4,4, 5,5-tetramethyl-1,3,2-dioxaphospholan-2-yl)oxy]biphenyl-κ2 P,P′}hydrido(triphenylphosphane-κP)rhodium(I) diethyl ether trisolvate. 2013. Chester : International Union of Crystallography
Selent, D., Spannenberg, A. and Börner, A. (2013) “Carbonyl{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(4,4, 5,5-tetramethyl-1,3,2-dioxaphospholan-2-yl)oxy]biphenyl-κ2 P,P′}hydrido(triphenylphosphane-κP)rhodium(I) diethyl ether trisolvate.” Chester : International Union of Crystallography. doi: https://doi.org/10.1107/S1600536812049124.
Selent D, Spannenberg A, Börner A. Carbonyl{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(4,4, 5,5-tetramethyl-1,3,2-dioxaphospholan-2-yl)oxy]biphenyl-κ2 P,P′}hydrido(triphenylphosphane-κP)rhodium(I) diethyl ether trisolvate. Vol. 69. Chester : International Union of Crystallography; 2013.
Selent, D., Spannenberg, A., & Börner, A. (2013). Carbonyl{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(4,4, 5,5-tetramethyl-1,3,2-dioxaphospholan-2-yl)oxy]biphenyl-κ2 P,P′}hydrido(triphenylphosphane-κP)rhodium(I) diethyl ether trisolvate (Version publishedVersion, Vol. 69). Version publishedVersion, Vol. 69. Chester : International Union of Crystallography. https://doi.org/https://doi.org/10.1107/S1600536812049124
Selent D, Spannenberg A, Börner A. Carbonyl{3,3′-di-tert-butyl-5,5′-dimethoxy-2,2′-bis[(4,4, 5,5-tetramethyl-1,3,2-dioxaphospholan-2-yl)oxy]biphenyl-κ2 P,P′}hydrido(triphenylphosphane-κP)rhodium(I) diethyl ether trisolvate. 2013;69(1). doi:https://doi.org/10.1107/S1600536812049124


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