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| Title: | {2-[Bis(2,4-di-tert-butylphenoxy)-phosphanyloxy-κP]-3, 5-di-tert-butylphenyl-κC 1}[(1,2,5,6-η)-cycloocta-1,5-diene] rhodium(I) toluene monosolvate |
| Authors: | Selent, D.; Spannenberg, A.; Börner, A. |
| Publishers version: | https://doi.org/10.1107/S1600536812002851 |
| URI: | https://doi.org/10.34657/4254 https://oa.tib.eu/renate/handle/123456789/5625 |
| Issue Date: | 2012 |
| Published in: | Acta Crystallographica Section E: Structure Reports Online 68 (2012), 2 |
| Publisher: | Chester : International Union of Crystallography |
| Abstract: | The reaction of (η 3-allyl)[(1,2,5,6-η)-cycloocta-1,5- diene]rhodium(I) with tris-(2,4-di-tert-butylphenyl)phosphite in toluene produces the title compound, [Rh(C 42H 62O 3P)(C 8H 12)]·C 7H 8, by spontaneous metallation at one of the nonsubstituted phenyl ortho-C atoms of the phosphite molecule. The coordination geometry at the Rh I ion is distorted squareplanar. The toluene solvent molecule is disordered over two different orientations, with site-occupation factors of 0.810 (2) and 0.190 (2). |
| Keywords: | data-toparameter ratio = 19.3; disorder in solvent or counterion; mean σ(C-C) = 0.003 Å; R factor = 0.027; single-crystal X-ray study; T = 150 K; wR factor = 0.069 |
| Type: | article; Text |
| Publishing status: | publishedVersion |
| DDC: | 540 |
| License: | CC BY 4.0 Unported |
| Link to license: | https://creativecommons.org/licenses/by/4.0/ |
| Appears in Collections: | Chemie |
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Selent, D., A. Spannenberg and A. Börner, 2012. {2-[Bis(2,4-di-tert-butylphenoxy)-phosphanyloxy-κP]-3, 5-di-tert-butylphenyl-κC 1}[(1,2,5,6-η)-cycloocta-1,5-diene] rhodium(I) toluene monosolvate. 2012. Chester : International Union of Crystallography
Selent, D., Spannenberg, A. and Börner, A. (2012) “{2-[Bis(2,4-di-tert-butylphenoxy)-phosphanyloxy-κP]-3, 5-di-tert-butylphenyl-κC 1}[(1,2,5,6-η)-cycloocta-1,5-diene] rhodium(I) toluene monosolvate.” Chester : International Union of Crystallography. doi: https://doi.org/10.1107/S1600536812002851.
Selent D, Spannenberg A, Börner A. {2-[Bis(2,4-di-tert-butylphenoxy)-phosphanyloxy-κP]-3, 5-di-tert-butylphenyl-κC 1}[(1,2,5,6-η)-cycloocta-1,5-diene] rhodium(I) toluene monosolvate. Vol. 68. Chester : International Union of Crystallography; 2012.
Selent, D., Spannenberg, A., & Börner, A. (2012). {2-[Bis(2,4-di-tert-butylphenoxy)-phosphanyloxy-κP]-3, 5-di-tert-butylphenyl-κC 1}[(1,2,5,6-η)-cycloocta-1,5-diene] rhodium(I) toluene monosolvate (Version publishedVersion, Vol. 68). Version publishedVersion, Vol. 68. Chester : International Union of Crystallography. https://doi.org/https://doi.org/10.1107/S1600536812002851
Selent D, Spannenberg A, Börner A. {2-[Bis(2,4-di-tert-butylphenoxy)-phosphanyloxy-κP]-3, 5-di-tert-butylphenyl-κC 1}[(1,2,5,6-η)-cycloocta-1,5-diene] rhodium(I) toluene monosolvate. 2012;68(2). doi:https://doi.org/10.1107/S1600536812002851
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