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Title: {2-[Bis(2,4-di-tert-butylphenoxy)-phosphanyloxy-κP]-3, 5-di-tert-butylphenyl-κC 1}[(1,2,5,6-η)-cycloocta-1,5-diene] rhodium(I) toluene monosolvate
Authors: Selent, D.Spannenberg, A.Börner, A.
Publishers version: https://doi.org/10.1107/S1600536812002851
URI: https://doi.org/10.34657/4254
https://oa.tib.eu/renate/handle/123456789/5625
Issue Date: 2012
Published in: Acta Crystallographica Section E: Structure Reports Online 68 (2012), 2
Publisher: Chester : International Union of Crystallography
Abstract: The reaction of (η 3-allyl)[(1,2,5,6-η)-cycloocta-1,5- diene]rhodium(I) with tris-(2,4-di-tert-butylphenyl)phosphite in toluene produces the title compound, [Rh(C 42H 62O 3P)(C 8H 12)]·C 7H 8, by spontaneous metallation at one of the nonsubstituted phenyl ortho-C atoms of the phosphite molecule. The coordination geometry at the Rh I ion is distorted squareplanar. The toluene solvent molecule is disordered over two different orientations, with site-occupation factors of 0.810 (2) and 0.190 (2).
Keywords: data-toparameter ratio = 19.3; disorder in solvent or counterion; mean σ(C-C) = 0.003 Å; R factor = 0.027; single-crystal X-ray study; T = 150 K; wR factor = 0.069
Type: article; Text
Publishing status: publishedVersion
DDC: 540
License: CC BY 4.0 Unported
Link to license: https://creativecommons.org/licenses/by/4.0/
Appears in Collections:Chemie

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Selent, D., A. Spannenberg and A. Börner, 2012. {2-[Bis(2,4-di-tert-butylphenoxy)-phosphanyloxy-κP]-3, 5-di-tert-butylphenyl-κC 1}[(1,2,5,6-η)-cycloocta-1,5-diene] rhodium(I) toluene monosolvate. 2012. Chester : International Union of Crystallography
Selent, D., Spannenberg, A. and Börner, A. (2012) “{2-[Bis(2,4-di-tert-butylphenoxy)-phosphanyloxy-κP]-3, 5-di-tert-butylphenyl-κC 1}[(1,2,5,6-η)-cycloocta-1,5-diene] rhodium(I) toluene monosolvate.” Chester : International Union of Crystallography. doi: https://doi.org/10.1107/S1600536812002851.
Selent D, Spannenberg A, Börner A. {2-[Bis(2,4-di-tert-butylphenoxy)-phosphanyloxy-κP]-3, 5-di-tert-butylphenyl-κC 1}[(1,2,5,6-η)-cycloocta-1,5-diene] rhodium(I) toluene monosolvate. Vol. 68. Chester : International Union of Crystallography; 2012.
Selent, D., Spannenberg, A., & Börner, A. (2012). {2-[Bis(2,4-di-tert-butylphenoxy)-phosphanyloxy-κP]-3, 5-di-tert-butylphenyl-κC 1}[(1,2,5,6-η)-cycloocta-1,5-diene] rhodium(I) toluene monosolvate (Version publishedVersion, Vol. 68). Version publishedVersion, Vol. 68. Chester : International Union of Crystallography. https://doi.org/https://doi.org/10.1107/S1600536812002851
Selent D, Spannenberg A, Börner A. {2-[Bis(2,4-di-tert-butylphenoxy)-phosphanyloxy-κP]-3, 5-di-tert-butylphenyl-κC 1}[(1,2,5,6-η)-cycloocta-1,5-diene] rhodium(I) toluene monosolvate. 2012;68(2). doi:https://doi.org/10.1107/S1600536812002851


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