Atmospheric band fitting coefficients derived from a self-consistent rocket-borne experiment

Abstract

Based on self-consistent rocket-borne measurements of temperature, the densities of atomic oxygen and neutral air, and the volume emission of the atmospheric band (762 nm), we examined the one-step and two-step excitation mechanism of O2 + b16C g for nighttime conditions. Following McDade et al. (1986), we derived the empirical fitting coefficients, which parameterize the atmospheric band emission O2 + b16C g X36 g .0;0/. This allows us to derive the atomic oxygen concentration from nighttime observations of atmospheric band emission O2 + b16C g X36 g .0; 0/. The derived empirical parameters can also be utilized for atmospheric band modeling. Additionally, we derived the fit function and corresponding coefficients for the combined (one- and two-step) mechanism. The simultaneous common volume measurements of all the parameters involved in the theoretical calculation of the observed O2 + b16C g X36 g .0; 0/ emission, i.e., temperature and density of the background air, atomic oxygen density, and volume emission rate, is the novelty and the advantage of this work. © Author(s) 2019.

Description
Keywords
atmospheric chemistry, concentration (composition), empirical analysis, experimental study, oxygen, temperature effect
Citation
Grygalashvyly, M., Eberhart, M., Hedin, J., Strelnikov, B., Lübken, F.-J., Rapp, M., et al. (2019). Atmospheric band fitting coefficients derived from a self-consistent rocket-borne experiment. 19(2). https://doi.org//10.5194/acp-19-1207-2019
License
CC BY 4.0 Unported