High Blocking Temperature of Magnetization and Giant Coercivity in the Azafullerene Tb 2 @C 79 N with a Single-Electron Terbium–Terbium Bond
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Date
2019
Volume
58
Issue
18
Journal
Series Titel
Book Title
Publisher
Weinheim : Wiley-VCH
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Abstract
The azafullerene Tb 2 @C 79 N is found to be a single-molecule magnet with a high 100-s blocking temperature of magnetization of 24 K and large coercivity. Tb magnetic moments with an easy-axis single-ion magnetic anisotropy are strongly coupled by the unpaired spin of the single-electron Tb−Tb bond. Relaxation of magnetization in Tb 2 @C 79 N below 15 K proceeds via quantum tunneling of magnetization with the characteristic time τ QTM =16 462±1230 s. At higher temperature, relaxation follows the Orbach mechanism with a barrier of 757±4 K, corresponding to the excited states, in which one of the Tb spins is flipped. © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.
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Keywords
endohedral fullerenes, exchange coupling, metal–metal bonds, single-molecule magnets, terbium
Citation
Velkos, G., Krylov, D. S., Kirkpatrick, K., Spree, L., Dubrovin, V., Büchner, B., et al. (2019). High Blocking Temperature of Magnetization and Giant Coercivity in the Azafullerene Tb 2 @C 79 N with a Single-Electron Terbium–Terbium Bond. 58(18). https://doi.org//10.1002/anie.201900943
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CC BY-NC 4.0 Unported