Accessing heavy allyl-analogous [(TerN)2E]− (E = Sb, Bi) ions and their reactivity towards ECl3

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Date
2015
Volume
51
Issue
57
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Publisher
Cambridge : Soc.
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Abstract

The attempted preparation of the biradicaloid [E(μ-NTer)]2 (E = Sb, Bi) yielded salts of the anion [(TerN)2E]−. These heteroatom allyl analogues could be further utilized in the reaction with pnictogen(III) chlorides to form the first 1,3-dichloro-1-bisma-3-stiba-2,4-diazane [ClSb(μ-NTer)2BiCl].

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Keywords
1,3 dichloro 1 bisma 3 stiba 2,4 diazane, allyl compound, anion, chloride, inorganic salt, ion, unclassified drug, chemical reaction, chemical structure
Citation
Hinz, A., Schulz, A., & Villinger, A. (2015). Accessing heavy allyl-analogous [(TerN)2E]− (E = Sb, Bi) ions and their reactivity towards ECl3. 51(57). https://doi.org//10.1039/c5cc04355g
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CC BY 3.0 Unported