Brønsted acid-catalyzed hydroarylation of activated olefins

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Brønsted_acid-catalyzed_hydroarylation_of_activated_olefins.pdf(336.24 KB)
Date
2014
Authors
Volume
5
Issue
1
Journal
Series Titel
Book Title
Publisher
London : RSC Publishing
Link to publishers version
https://doi.org/10.1039/c4ra13647k
Abstract

A mild, regiospecific Brønsted acid-catalyzed hydroarylation of activated olefins, capable of the formation of quinone methide-like intermediates, has been investigated. Variously substituted 2- and 4-vinylphenols, 4-vinylaniline or 6-vinyl-naphthalen-2-ol were successfully implemented in a sequential protonation and Friedel–Crafts-type alkylation reaction of electron-rich arenes.

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Keywords
Olefins, Activated olefins, Alkylation reactions, Electron-rich arenes, Friedel-Crafts, Hydroarylation, Quinone methide, Regiospecific, Catalysis
URI
https://oa.tib.eu/renate/handle/123456789/9264
 https://doi.org/10.34657/8302
Citation
Fleischer, I., & Pospech, J. (2014). Brønsted acid-catalyzed hydroarylation of activated olefins. 5(1). https://doi.org//10.1039/c4ra13647k
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Chemie
License
CC BY 3.0 Unported
https://creativecommons.org/licenses/by/3.0/