Brønsted acid-catalyzed hydroarylation of activated olefins

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Volume

5

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1

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RSC Advances : an international journal to further the chemical sciences

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London : RSC Publishing

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Abstract

A mild, regiospecific Brønsted acid-catalyzed hydroarylation of activated olefins, capable of the formation of quinone methide-like intermediates, has been investigated. Variously substituted 2- and 4-vinylphenols, 4-vinylaniline or 6-vinyl-naphthalen-2-ol were successfully implemented in a sequential protonation and Friedel–Crafts-type alkylation reaction of electron-rich arenes.

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CC BY 3.0 Unported