On the interaction between oxygen, iron and sulfur in industrial glass melts

dc.bibliographicCitation.firstPage297
dc.bibliographicCitation.journalTitleGlass Science and Technologyeng
dc.bibliographicCitation.lastPage303
dc.bibliographicCitation.volume67
dc.contributor.authorMüller-Simon, Hayo
dc.date.accessioned2024-01-08T09:59:56Z
dc.date.available2024-01-08T09:59:56Z
dc.date.issued1994
dc.description.abstractThe oxidation state of iron in industrially molten glasses has been investigated in the cold glass and related to the oxygen activity in the glass melt. The prediction of the oxidation state of iron in the cold glass from the measured oxygen activity in the glass melt is disturbed in such a way that in oxidized molten glasses the Fe²⁺ content and in amber glasses the Fe³⁺ content increase during cooling. This behavior can be explained by an interaction due to the oxidation reactions of sulfur known from the literature during cooling. The reaction constants result in electrochemical standard potentials which agree with voltammetric studies.eng
dc.description.versionpublishedVersion
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/14398
dc.identifier.urihttps://doi.org/10.34657/13428
dc.language.isoeng
dc.publisherOffenbach : Verlag der Deutschen Glastechnischen Gesellschaft
dc.relation.issn0946-7475
dc.rights.licenseCC BY 3.0 DE
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/de/
dc.subject.ddc660
dc.titleOn the interaction between oxygen, iron and sulfur in industrial glass meltseng
dc.typeArticleeng
dc.typeTexteng
tib.accessRightsopenAccess
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