The effect of supported MoOX structures on the reaction pathways of propene formation in the metathesis of ethylene and 2-butene
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Date
2014
Authors
Volume
50
Issue
65
Journal
Series Titel
Book Title
Publisher
Cambridge : RSC
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Abstract
The kind of surface MoOX structures on Al2O3–SiO2 was found to determine propene selectivity in the metathesis of ethylene and 2-butene. Compared to isolated tetrahedral MoOX species, their polymerized octahedral counterparts show significantly lower activity for isomerisation of 2- to 1-butene thus hindering non-selective metathesis of these butenes. In addition, they reveal higher ability to engage ethylene in propene formation.
Description
Keywords
butane, ethylene, propylene, article, catalyst, chemical reaction, chemical structure, dimerization, isomerization, metathesis, polymerization, pressure, reaction analysis, surface property
Citation
Hahn, T., Kondratenko, E. V., & Linke, D. (2014). The effect of supported MoOX structures on the reaction pathways of propene formation in the metathesis of ethylene and 2-butene. 50(65). https://doi.org//10.1039/c4cc01827c
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License
CC BY 3.0 Unported