Crystal structure of di-n-but­yl­bis­([eta]5-penta­methyl­cyclo­penta­dien­yl)hafnium(IV)

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dc.bibliographicCitation.firstPagem19
dc.bibliographicCitation.issue2
dc.bibliographicCitation.lastPagem20
dc.bibliographicCitation.volumeE71
dc.contributor.authorArndt, Perdita
dc.contributor.authorSchubert,Kathleen
dc.contributor.authorBurlakov, Vladimir V.
dc.contributor.authorSpannenberg, Anke
dc.contributor.authorRosenthal, Uwe
dc.date.accessioned2022-06-27T08:33:48Z
dc.date.available2022-06-27T08:33:48Z
dc.date.issued2015
dc.description.abstractThe crystal structure of the title compound, [Hf(C10H15)2(C4H9)2], reveals two independent mol­ecules in the asymmetric unit. The diffraction experiment was performed with a racemically twinned crystal showing a 0.529 (5):0.471 (5) component ratio. Each HfIV atom is coordinated by two penta­methyl­cyclo­penta­dienyl and two n-butyl ligands in a distorted tetra­hedral geometry, with the cyclo­penta­dienyl rings inclined to one another by 45.11 (15) and 45.37 (16)°. In contrast to the isostructural di(n-butyl)bis([eta]5-penta­methyl­cyclo­penta­dien­yl)zirconium(IV) complex with a noticeable difference in the Zr-butyl bonding, the Hf-Cbut­yl bond lengths differ from each other by no more than 0.039 (3) Å.eng
dc.description.versionpublishedVersioneng
dc.identifier.urihttps://oa.tib.eu/renate/handle/123456789/9282
dc.identifier.urihttps://doi.org/10.34657/8320
dc.language.isoengeng
dc.publisherChester : International Union of Crystallography
dc.relation.doihttps://doi.org/10.1107/S2056989015000092
dc.relation.essn2056-9890
dc.relation.ispartofseriesActa crystallographica : Section E, Crystallographic communications E71 (2015), Nr. 2
dc.rights.licenseCC BY 2.0 UK
dc.rights.urihttps://creativecommons.org/licenses/by/2.0/uk/
dc.subjectCrystal structureeng
dc.subjectHafnoceneeng
dc.subjectN-butyleng
dc.subjectRacemic twineng
dc.subject.ddc530
dc.titleCrystal structure of di-n-but­yl­bis­([eta]5-penta­methyl­cyclo­penta­dien­yl)hafnium(IV)eng
dc.typearticleeng
dc.typeTexteng
dcterms.bibliographicCitation.journalTitleActa crystallographica : Section E, Crystallographic communications
local.doifilter.overrideja
tib.accessRightsopenAccesseng
wgl.contributorLIKATger
wgl.subjectPhysikger
wgl.subjectChemieger
wgl.typeZeitschriftenartikelger
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