Cononsolvency Transition of Polymer Brushes: A Combined Experimental and Theoretical Study
dc.bibliographicCitation.firstPage | 991 | |
dc.bibliographicCitation.issue | 6 | |
dc.bibliographicCitation.journalTitle | Materials | eng |
dc.bibliographicCitation.volume | 11 | |
dc.contributor.author | Yong, Huaisong | |
dc.contributor.author | Rauch, Sebastian | |
dc.contributor.author | Eichhorn, Klaus-Jochen | |
dc.contributor.author | Uhlmann, Petra | |
dc.contributor.author | Fery, Andreas | |
dc.contributor.author | Sommer, Jens-Uwe | |
dc.date.accessioned | 2023-01-25T09:58:49Z | |
dc.date.available | 2023-01-25T09:58:49Z | |
dc.date.issued | 2018 | |
dc.description.abstract | In this study, the cononsolvency transition of poly(N-isopropylacrylamide) (PNiPAAm) brushes in aqueous ethanol mixtures was studied by using Vis-spectroscopic ellipsometry (SE) discussed in conjunction with the adsorption-attraction model. We proved that the cononsolvency transition of PNiPAAm brushes showed features of a volume phase transition, such as a sharp collapse, reaching a maximum decrease in thickness for a very narrow ethanol volume composition range of 15% to 17%. These observations are in agreement with the recently published preferential adsorption model of the cononsolvency effect. | eng |
dc.description.version | publishedVersion | eng |
dc.identifier.uri | https://oa.tib.eu/renate/handle/123456789/11057 | |
dc.identifier.uri | http://dx.doi.org/10.34657/10083 | |
dc.language.iso | eng | |
dc.publisher | Basel : MDPI | |
dc.relation.doi | https://doi.org/10.3390/ma11060991 | |
dc.relation.essn | 1996-1944 | |
dc.rights.license | CC BY 4.0 Unported | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | |
dc.subject.ddc | 600 | |
dc.subject.other | Cononsolvency | eng |
dc.subject.other | Ellipsometry | eng |
dc.subject.other | PNiPAAm | eng |
dc.subject.other | Polymer brushes | eng |
dc.subject.other | Preferential adsorption | eng |
dc.title | Cononsolvency Transition of Polymer Brushes: A Combined Experimental and Theoretical Study | eng |
dc.type | Article | eng |
dc.type | Text | eng |
tib.accessRights | openAccess | |
wgl.contributor | IPF | |
wgl.subject | Ingenieurwissenschaften | ger |
wgl.subject | Chemie | ger |
wgl.type | Zeitschriftenartikel | ger |
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