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- ItemFrom nonlinear to linear elasticity in a coupled rate-dependent/independent system for brittle delamination(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2017) Rossi, Riccarda; Thomas, MaritaWe revisit the weak, energetic-type existence results obtained in [RT15] for a system for rateindependent, brittle delamination between two visco-elastic, physically nonlinear bulk materials and explain how to rigorously extend such results to the case of visco-elastic, linearly elastic bulk materials. Our approximation result is essentially based on deducing the MOSCO-convergence of the functionals involved in the energetic formulation of the system. We apply this approximation result in two different situations at small strains: Firstly, to pass from a nonlinearly elastic to a linearly elastic, brittle model on the time-continuous level, and secondly, to pass from a time-discrete to a time-continuous model using an adhesive contact approximation of the brittle model, in combination with a vanishing, super-quadratic regularization of the bulk energy. The latter approach is beneficial if the model also accounts for the evolution of temperature.
- ItemLarge deviations of specific empirical fluxes of independent Markov chains, with implications for Macroscopic Fluctuation Theory(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2017) Renger, D.R. MichielWe consider a system of independent particles on a finite state space, and prove a dynamic large-deviation principle for the empirical measure-empirical flux pair, taking the specific fluxes rather than net fluxes into account. We prove the large deviations under deterministic initial conditions, and under random initial conditions satisfying a large-deviation principle. We then show how to use this result to generalise a number of principles from Macroscopic Fluctuation Theory to the finite-space setting.
- ItemPhase sensitive excitability of a limit cycle(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2017) Franovic, Igor; Omelchenko, Oleh E.; Wolfrum, MatthiasThe classical notion of excitability refers to an equilibrium state that shows under the influence of perturbations a nonlinear threshold-like behavior. Here, we extend this concept by demonstrating how periodic orbits can exhibit a specific form of excitable behavior where the nonlinear threshold-like response appears only after perturbations applied within a certain part of the periodic orbit, i.e the excitability happens to be phase sensitive. As a paradigmatic example of this concept we employ the classical FitzHugh-Nagumo system. The relaxation oscillations, appearing in the oscillatory regime of this system, turn out to exhibit a phase sensitive nonlinear thresholdlike response to perturbations, which can be explained by the nonlinear behavior in the vicinity of the canard trajectory. Triggering the phase sensitive excitability of the relaxation oscillations by noise we find a characteristic non-monotone dependence of the mean spiking rate of the relaxation oscillation on the noise level. We explain this non-monotone dependence as a result of an interplay of two competing effects of the increasing noise: the growing efficiency of the excitation and the degradation of the nonlinear response.
- ItemAnalysis of improved Nernst-Planck-Poisson models of compressible isothermal electrolytes. Part II: Approximation and a priori estimates(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2017) Dreyer, Wolfgang; Druet, Pierre-Étienne; Gajewski, Paul; Guhlke, ClemensWe consider an improved NernstPlanckPoisson model first proposed by Dreyer et al. in 2013 for compressible isothermal electrolytes in non equilibrium. The model takes into account the elastic deformation of the medium that induces an inherent coupling of mass and momentum transport. The model consists of convectiondiffusionreaction equations for the constituents of the mixture, of the Navier-Stokes equation for the barycentric velocity, and of the Poisson equation for the electrical potential. Due to the principle of mass conservation, crossdiffusion phenomena must occur and the mobility matrix (Onsager matrix) has a kernel. In this paper, which continues the investigation of [DDGG17a], we derive for thermodynamically consistent approximation schemes the natural uniform estimates associated with the dissipations. Our results essentially improve our former study [DDGG16], in particular the a priori estimates concerning the relative chemical potentials.
- ItemAnalysis of improved Nernst-Planck-Poisson models of compressible isothermal electrolytes. Part I: Derivation of the model and survey of the results(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2017) Dreyer, Wolfgang; Druet, Pierre-Étienne; Gajewski, Paul; Guhlke, ClemensWe consider an improved NernstPlanckPoisson model first proposed by Dreyer et al. in 2013 for compressible isothermal electrolytes in non equilibrium. The model takes into account the elastic deformation of the medium that induces an inherent coupling of mass and momentum transport. The model consists of convectiondiffusionreaction equations for the constituents of the mixture, of the Navier-Stokes equation for the barycentric velocity, and of the Poisson equation for the electrical potential. Due to the principle of mass conservation, crossdiffusion phenomena must occur and the mobility matrix (Onsager matrix) has a kernel. In this paper we establish the existence of a globalintime weak solution for the full model, allowing for a general structure of the mobility tensor and for chemical reactions with highly non linear rates in the bulk and on the active boundary. We characterise the singular states of the system, showing that the chemical species can vanish only globally in space, and that this phenomenon must be concentrated in a compact set of measure zero in time. With respect to our former study [DDGG16], we also essentially improve the a priori estimates, in particular concerning the relative chemical potentials.
- ItemLocal well-posedness for thermodynamically motivated quasilinear parabolic systems in divergence form(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2017) Druet, Pierre-ÉtienneWe show that fully quasilinear parabolic systems are locally well posed in the Hilbert space scala if the coefficients of the differential operator are smooth enough and the spatial domain is sufficiently regular. In the context of diffusion systems driven by entropy, the uniform parabolicity follows from the second law of thermodynamics.
- ItemGlobal-in-time solvability of thermodynamically motivated parabolic systems(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2017) Druet, Pierre-ÉtienneIn this paper, doubly non linear parabolic systems in divergence form are investigated form the point of view of their global-in-time weak solvability. The non-linearity under the time derivative is given by the gradient of a strictly convex, globally Lipschitz continuous potential, multiplied by a position-dependent weight. This weight admits singular values. The flux under the spatial divergence is also of monotone gradient type, but it is not restricted to polynomial growth. It is assumed that the elliptic operator generates some equi-coercivity on the spatial derivatives of the unknowns. The paper introduces some original techniques to deal with the case of nonlinear purely Neumann boundary conditions. In this respect, it generalises or complements the results by Alt and Luckhaus (1983) and Alt (2012). A field of application of the theory are the multi species diffusion systems driven by entropy.
- ItemThe weighted energy-dissipation principle and evolutionary [Gamma]-convergence for doubly nonlinear problems(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2017) Liero, Matthias; Melchionna, StefanoWe consider a family of doubly nonlinear evolution equations that is given by families of convex dissipation potentials, nonconvex energy functionals, and external forces parametrized by a small parameter ε. For each of these problems, we introduce the so-called weighted energy-dissipation (WED) functional, whose minimizer correspond to solutions of an elliptic-in-time regularization of the target problems with regularization parameter δ. We investigate the relation between the Γ-convergence of the WED functionals and evolutionary Γ-convergence of the associated systems. More precisely, we deal with the limits δ→0, ε→0, as well as δ+ ε→0 either in the sense of Γ-convergence of functionals or in the sense of evolutionary Γ-convergence of functional-driven evolution problems, or both. Additionally, we provide some quantitative estimates on the rate of convergence for the limit ε→0, in the case of quadratic dissipation potentials and uniformly λ-convex energy functionals. Finally, we discuss a homogenization problem as an example of application.
- ItemEmbedding the dynamics of a single delay system into a feed-forward ring(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2017) Klinshov, Vladimir; Shchapin, Dmitry; Yanchuk, Serhiy; Wolfrum, Matthias; D'Huys, Otti; Nekorkin, VladimirWe investigate the relation between the dynamics of a single oscillator with delayed selffeedback and a feed-forward ring of such oscillators, where each unit is coupled to its next neighbor in the same way as in the self-feedback case. We show that periodic solutions of the delayed oscillator give rise to families of rotating waves with different wave numbers in the corresponding ring. In particular, if for the single oscillator the periodic solution is resonant to the delay, it can be embedded into a ring with instantaneous couplings. We discover several cases where stability of periodic solution for the single unit can be related to the stability of the corresponding rotating wave in the ring. As a specific example we demonstrate how the complex bifurcation scenario of simultaneously emerging multi-jittering solutions can be transferred from a single oscillator with delayed pulse feedback to multi-jittering rotating waves in a sufficiently large ring of oscillators with instantaneous pulse coupling. Finally, we present an experimental realization of this dynamical phenomenon in a system of coupled electronic circuits of FitzHughNagumo type.
- ItemOn the dissociation degree of ionic solutions considering solvation effects(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2017) Landstorfer, ManuelIn this work the impact of solvation effects on the dissociation degree of strong electrolytes and salts is discussed. The investigation is based on a thermodynamic model which is capable to predict qualitatively and quantitatively the double layer capacity of various electrolytes. A remarkable relationship between capacity maxima, partial molar volume of ions in solution, and solvation numbers, provides an experimental access to determine the number of solvent molecules bound to a specific ion in solution. This shows that the Stern layer is actually a saturated solution of 1 mol L 1 solvated ions, and we point out some fundamental similarities of this state to a saturated bulk solution. Our finding challenges the assumption of complete dissociation, even for moderate electrolyte concentrations, whereby we introduce an undissociated ion-pair in solution. We re-derive the equilibrium conditions for a two-step dissociation reaction, including solvation effects, which leads to a new relation to determine the dissociation degree. A comparison to Ostwalds dilution law clearly shows the shortcomings when solvation effects are neglected and we emphasize that complete dissociation is questionable beyond 0.5 mol L 1 for aqueous, mono-valent electrolytes.