Search Results
The effect of supported MoOX structures on the reaction pathways of propene formation in the metathesis of ethylene and 2-butene
2014, Hahn, T., Kondratenko, E.V., Linke, D.
The kind of surface MoOX structures on Al2O3–SiO2 was found to determine propene selectivity in the metathesis of ethylene and 2-butene. Compared to isolated tetrahedral MoOX species, their polymerized octahedral counterparts show significantly lower activity for isomerisation of 2- to 1-butene thus hindering non-selective metathesis of these butenes. In addition, they reveal higher ability to engage ethylene in propene formation.
Accessing heavy allyl-analogous [(TerN)2E]− (E = Sb, Bi) ions and their reactivity towards ECl3
2015, Hinz, Alexander, Schulz, Axel, Villinger, Alexander
The attempted preparation of the biradicaloid [E(μ-NTer)]2 (E = Sb, Bi) yielded salts of the anion [(TerN)2E]−. These heteroatom allyl analogues could be further utilized in the reaction with pnictogen(III) chlorides to form the first 1,3-dichloro-1-bisma-3-stiba-2,4-diazane [ClSb(μ-NTer)2BiCl].