2014, Burghoorn, M., Kniknie, B., van Deelen, J., Xu, M., Vroon, Z., van Ee, R., van de Belt, R., Buskens, P.

Textured transparent conductors are widely used in thin-film silicon solar cells. They lower the reflectivity at interfaces between different layers in the cell and/or cause an increase in the path length of photons in the Si absorber layer, which both result in an increase in the number of absorbed photons and, consequently, an increase in short-circuit current density (Jsc) and cell efficiency. Through optical simulations, we recently obtained strong indications that texturing of the transparent conductor in copper indium gallium (di-)selenide (CIGS) solar cells is also optically advantageous. Here, we experimentally demonstrate that the Jsc and efficiency of CIGS solar cells with an absorber layer thickness (dCIGS) of 0.85 μm, 1.00 μm and 2.00 μm increase through application of a moth-eye textured resist with a refractive index that is sufficiently similar to AZO (nresist = 1.792 vs. nAZO = 1.913-at 633 nm) to avoid large optical losses at the resist-AZO interface. On average, Jsc increases by 7.2%, which matches the average reduction in reflection of 7.0%. The average relative increase in efficiency is slightly lower (6.0%). No trend towards a larger relative increase in Jsc with decreasing dCIGS was observed. Ergo, the increase in Jsc can be fully explained by the reduction in reflection, and we did not observe any increase in Jsc based on an increased photon path length. © 2014 Author(s).

2019, Kuttner, Christian, Höller, Roland P. M., Quintanilla, Marta, Schnepf, Max J., Dulle, Martin, Fery, Andreas, Liz-Marzán, Luis M.

The optical properties of nanoparticle assemblies can be tailored via hybridization of plasmon modes. Isotropic core/satellite superstructures made of spherical nanoparticles are known to exhibit coupled modes with a strongly scattering (radiative) character, and provide hot spots yielding high activity in surface-enhanced Raman scattering (SERS). However, to complement this functionality with plasmonic heating, additional absorbing (non-radiative) modes are required. We introduce herein anisotropic superstructures formed by decorating a central nanorod with spherical satellite nanoparticles, which feature two coupled modes that allow application for both SERS and heating. On the basis of diffuse reflectance spectroscopy, small-angle X-ray scattering (SAXS), and electromagnetic simulations, the origin of the coupled modes is disclosed and thus serves as a basis toward alternative designs of functional superstructures. This work represents a proof-of-principle for the combination of high SERS efficiency with efficient plasmonic heating by near-infrared irradiation.

2021, Davenport, John J., Diab, Momen, Deka, Pranab J., Tripathi, Aashana, Madhav, Kalaga, Roth, Martin M.

We present a detailed method of tapering and drawing photonic lanterns using a filament glass processing system. Single-mode fibers (SMFs) were stacked inside a low refractive index, fluorine-doped capillary, which was then heated and tapered to produce a transition from single-mode to multi-mode. Fabrication parameters were considered in four categories: method of preparation and stacking of SMFs into a capillary, heat and filament dimensions of the glass processor, capillary ID, and the use of vacuum during tapering. 19- and 37- fiber lanterns were drawn, demonstrating good fusion between SMF claddings, a clear differentiation between core and cladding in the multimode (MM) section, and well-ordered arrangements between SMFs, which is controlled during the tapering process. The transmission efficiency of a 19-fiber photonic lantern, compared to an MMF with the same core diameter and NA, has a relative transmission efficiency of 1.19 dB or 67.1%. The steps and parameters provided in this paper form a framework for fabricating quality photonic lanterns.

2023, Zhang, Zongbao, Ji, Ran, Hofstetter, Yvonne J., Deconinck, Marielle, Brunner, Julius, Li, Yanxiu, An, Qingzhi, Vaynzof, Yana

Inorganic cesium lead iodide (CsPbI3) perovskite solar cells (PSCs) have attracted enormous attention due to their excellent thermal stability and optical bandgap (∼1.73 eV), well-suited for tandem device applications. However, achieving high-performance photovoltaic devices processed at low temperatures is still challenging. Here we reported a new method for the fabrication of high-efficiency and stable γ-CsPbI3 PSCs at lower temperatures than was previously possible by introducing the long-chain organic cation salt ethane-1,2-diammonium iodide (EDAI2) and regulating the content of lead acetate (Pb(OAc)2) in the perovskite precursor solution. We find that EDAI2 acts as an intermediate that can promote the formation of γ-CsPbI3, while excess Pb(OAc)2 can further stabilize the γ-phase of CsPbI3 perovskite. Consequently, improved crystallinity and morphology and reduced carrier recombination are observed in the CsPbI3 films fabricated by the new method. By optimizing the hole transport layer of CsPbI3 inverted architecture solar cells, we demonstrate efficiencies of up to 16.6%, surpassing previous reports examining γ-CsPbI3 in inverted PSCs. Notably, the encapsulated solar cells maintain 97% of their initial efficiency at room temperature and under dim light for 25 days, demonstrating the synergistic effect of EDAI2 and Pb(OAc)2 in stabilizing γ-CsPbI3 PSCs.

2021, Stenzel, Fabian, Gerten, Dieter, Hanasaki, Naota

Many scenarios of future climate evolution and its anthropogenic drivers include considerable amounts of bioenergy as a fuel source, as a negative emission technology, and for providing electricity. The associated freshwater abstractions for irrigation of dedicated biomass plantations might be substantial and therefore potentially increase water limitation and stress in affected regions; however, assumptions and quantities of water use provided in the literature vary strongly. This paper reviews existing global assessments of freshwater abstractions for bioenergy production and puts these estimates into the context of scenarios of other water-use sectors. We scanned the available literature and (out of 430 initial hits) found 16 publications (some of which include several bioenergy-water-use scenarios) with reported values on global irrigation water abstractions for biomass plantations, suggesting water withdrawals in the range of 128.4 to 9000 km3 yr−1, which would come on top of (or compete with) agricultural, industrial, and domestic water withdrawals. To provide an understanding of the origins of this large range, we present the diverse underlying assumptions, discuss major study differences, and calculate an inverse water-use efficiency (iwue), which facilitates comparison of the required freshwater amounts per produced biomass harvest. We conclude that due to the potentially high water demands and the tradeoffs that might go along with them, bioenergy should be an integral part of global assessments of freshwater demand and use. For interpreting and comparing reported estimates of possible future bioenergy water abstractions, full disclosure of parameters and assumptions is crucial. A minimum set should include the complete water balances of bioenergy production systems (including partitioning of blue and green water), bioenergy crop species and associated water-use efficiencies, rainfed and irrigated bioenergy plantation locations (including total area and meteorological conditions), and total biomass harvest amounts. In the future, a model intercomparison project with standardized parameters and scenarios would be helpful.

2020, Molkenthin, Nora, Schröder, Malte, Timme, Marc

Ride-sharing services may substantially contribute to future sustainable mobility. Their collective dynamics intricately depend on the topology of the underlying street network, the spatiotemporal demand distribution, and the dispatching algorithm. The efficiency of ride-sharing fleets is thus hard to quantify and compare in a unified way. Here, we derive an efficiency observable from the collective nonlinear dynamics and show that it exhibits a universal scaling law. For any given dispatcher, we find a common scaling that yields data collapse across qualitatively different topologies of model networks and empirical street networks from cities, islands, and rural areas. A mean-field analysis confirms this view and reveals a single scaling parameter that jointly captures the influence of network topology and demand distribution. These results further our conceptual understanding of the collective dynamics of ride-sharing fleets and support the evaluation of ride-sharing services and their transfer to previously unserviced regions or unprecedented demand patterns.

2012, Picco, A., Bonera, E., Pezzoli, F., Grilli, E., Schmidt, O.G., Isa, F., Cecchi, S., Guzzi, M.

In this work, we present an experimental procedure to measure the composition distribution within inhomogeneous SiGe nanostructures. The method is based on the Raman spectra of the nanostructures, quantitatively analyzed through the knowledge of the scattering efficiency of SiGe as a function of composition and excitation wavelength. The accuracy of the method and its limitations are evidenced through the analysis of a multilayer and of self-assembled islands.

2015, Jägermeyr, J., Gerten, D., Heinke, J., Schaphoff, S., Kummu, M., Lucht, W.

2021, Kleine, Carlo, Ekimova, Maria, Winghart, Marc-Oliver, Eckert, Sebastian, Reichel, Oliver, Löchel, Heike, Probst, Jürgen, Braig, Christoph, Seifert, Christian, Erko, Alexei, Sokolov, Andrey, Vrakking, Marc J. J., Nibbering, Erik T. J., Rouzée, Arnaud

We present a novel soft x-ray spectrometer for ultrafast absorption spectroscopy utilizing table-top femtosecond high-order harmonic sources. Where most commercially available spectrometers rely on spherical variable line space gratings with a typical efficiency on the order of 3% in the first diffractive order, this spectrometer, based on a Hettrick-Underwood design, includes a reflective zone plate as a dispersive element. An improved efficiency of 12% at the N K-edge is achieved, accompanied by a resolving power of 890. The high performance of the soft x-ray spectrometer is further demonstrated by comparing nitrogen K-edge absorption spectra from calcium nitrate in aqueous solution obtained with our high-order harmonic source to previous measurements performed at the electron storage ring facility BESSY II.