Search Results
Analysis of improved Nernst-Planck-Poisson models of compressible isothermal electrolytes. Part II: Approximation and a priori estimates
2017, Dreyer, Wolfgang, Druet, Pierre-Étienne, Gajewski, Paul, Guhlke, Clemens
We consider an improved NernstPlanckPoisson model first proposed by Dreyer et al. in 2013 for compressible isothermal electrolytes in non equilibrium. The model takes into account the elastic deformation of the medium that induces an inherent coupling of mass and momentum transport. The model consists of convectiondiffusionreaction equations for the constituents of the mixture, of the Navier-Stokes equation for the barycentric velocity, and of the Poisson equation for the electrical potential. Due to the principle of mass conservation, crossdiffusion phenomena must occur and the mobility matrix (Onsager matrix) has a kernel. In this paper, which continues the investigation of [DDGG17a], we derive for thermodynamically consistent approximation schemes the natural uniform estimates associated with the dissipations. Our results essentially improve our former study [DDGG16], in particular the a priori estimates concerning the relative chemical potentials.
Local well-posedness for thermodynamically motivated quasilinear parabolic systems in divergence form
2017, Druet, Pierre-Étienne
We show that fully quasilinear parabolic systems are locally well posed in the Hilbert space scala if the coefficients of the differential operator are smooth enough and the spatial domain is sufficiently regular. In the context of diffusion systems driven by entropy, the uniform parabolicity follows from the second law of thermodynamics.
Existence of solutions to a two-dimensional model for nonisothermal two-phase flows of incompressible fluids
2014, Eleuteri, Michela, Rocca, Elisabetta, Schimperna, Giulio
We consider a thermodynamically consistent diffuse interface model describing two-phase flows of incompressible fluids in a non-isothermal setting. The model was recently introduced in [12] where existence of weak solutions was proved in three space dimensions. Here, we aim at studying the properties of solutions in the two-dimensional case. In particular, we can show existence of global in time solutions satisfying a stronger formulation of the model with respect to the one considered in [12]. Moreover, we can admit slightly more general conditions on some material coefficients of the system.
Analysis of improved Nernst-Planck-Poisson models of isothermal compressible electrolytes subject to chemical reactions: The case of a degenerate mobility matrix
2016, Druet, Pierre-Etienne
We continue our investigations of the improved NernstPlanckPoisson model introduced in [DGM13]. In the paper [DDGG16] the analysis relies on the hypothesis that the mobility matrix has maximal rank under the constraint of mass conservation (rank N-1 for a mixture of N species). In this paper we allow for the case that the positive eigenvalues of the mobility matrix tend to zero along with the partial mass densities of certain species. In this approach the mobility matrix has a variable rank between zero and N-1 according to the number of locally available species. We set up a concept of weak solution able to deal with this scenario, showing in particular how to extend the fundamental notion of differences of chemical potentials that supports the modelling and the analysis in [DDGG16]. We prove the global-in-time existence in this solution class.
Global-in-time solvability of thermodynamically motivated parabolic systems
2017, Druet, Pierre-Étienne
In this paper, doubly non linear parabolic systems in divergence form are investigated form the point of view of their global-in-time weak solvability. The non-linearity under the time derivative is given by the gradient of a strictly convex, globally Lipschitz continuous potential, multiplied by a position-dependent weight. This weight admits singular values. The flux under the spatial divergence is also of monotone gradient type, but it is not restricted to polynomial growth. It is assumed that the elliptic operator generates some equi-coercivity on the spatial derivatives of the unknowns. The paper introduces some original techniques to deal with the case of nonlinear purely Neumann boundary conditions. In this respect, it generalises or complements the results by Alt and Luckhaus (1983) and Alt (2012). A field of application of the theory are the multi species diffusion systems driven by entropy.
Analysis of improved Nernst-Planck-Poisson models of compressible isothermal electrolytes. Part III: Compactness and convergence
2017, Dreyer, Wolfgang, Druet, Pierre-Étienne, Gajewski, Paul, Guhlke, Clemens
We consider an improved Nernst-Planck-Poisson model first proposed by Dreyer et al. in 2013 for compressible isothermal electrolytes in non equilibrium. The model takes into account the elastic deformation of the medium that induces an inherent coupling of mass and momentum transport. The model consists of convectiondiffusionreaction equations for the constituents of the mixture, of the Navier-Stokes equation for the barycentric velocity, and of the Poisson equation for the electrical potential. Due to the principle of mass conservation, crossdiffusion phenomena must occur and the mobility matrix (Onsager matrix) has a kernel. In this paper, which continues the investigations of [DDGG17a, DDGG17b], we prove the compactness of the solution vector, and existence and convergence for the approximation schemes. We point at simple structural PDE arguments as an adequate substitute to the AubinLions compactness Lemma and its generalisations: These familiar techniques attain their limit in the context of our model in which the relationship between time derivatives (transport) and diffusion gradients is highly non linear.
Analysis of improved Nernst-Planck-Poisson models of compressible isothermal electrolytes. Part I: Derivation of the model and survey of the results
2017, Dreyer, Wolfgang, Druet, Pierre-Étienne, Gajewski, Paul, Guhlke, Clemens
We consider an improved NernstPlanckPoisson model first proposed by Dreyer et al. in 2013 for compressible isothermal electrolytes in non equilibrium. The model takes into account the elastic deformation of the medium that induces an inherent coupling of mass and momentum transport. The model consists of convectiondiffusionreaction equations for the constituents of the mixture, of the Navier-Stokes equation for the barycentric velocity, and of the Poisson equation for the electrical potential. Due to the principle of mass conservation, crossdiffusion phenomena must occur and the mobility matrix (Onsager matrix) has a kernel. In this paper we establish the existence of a globalintime weak solution for the full model, allowing for a general structure of the mobility tensor and for chemical reactions with highly non linear rates in the bulk and on the active boundary. We characterise the singular states of the system, showing that the chemical species can vanish only globally in space, and that this phenomenon must be concentrated in a compact set of measure zero in time. With respect to our former study [DDGG16], we also essentially improve the a priori estimates, in particular concerning the relative chemical potentials.
Existence of weak solutions for improved Nernst-Planck-Poisson models of compressible reacting electrolytes
2016, Dreyer, Wolfgang, Druet, Pierre-Étienne, Gajewski, Paul, Guhlke, Clemens
We consider an improved Nernst-Planck-Poisson model for compressible electrolytes first proposed by Dreyer et al. in 2013. The model takes into account the elastic deformation of the medium. In particular, large pressure contributions near electrochemical interfaces induce an inherent coupling of mass and momentum transport. The model consists of convection-diffusion-reaction equations for the constituents of the mixture, of the Navier-Stokes equation for the barycentric velocity and the Poisson equation for the electrical potential. Cross-diffusion phenomena occur due to the principle of mass conservation. Moreover, the diffusion matrix (mobility matrix) has a zero eigenvalue, meaning that the system is degenerate parabolic. In this paper we establish the existence of a global-in-time weak solution for the full model, allowing for cross-diffusion and an arbitrary number of chemical reactions in the bulk and on the active boundary.