Synthesis and crystallographic characterization of [2,2-bis(η5-pentamethylcyclopentadienyl)-3,4-bis(trimethylsilyl)-2-zirconafuran-5-one-κO5]triisobutylaluminium
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Date
2018-3-27
Volume
74
Issue
4
Journal
Series Titel
Book Title
Publisher
Chester : International Union of Crystallography
Link to publishers version
Abstract
The crystal structure of the title zwitterionic zirconocene complex containing a furanone unit, [AlZr(C10H15)2(C4H9)3(C9H18O2Si2)], is reported. On reacting a zirconafuranone with two equivalents of HAl(i-Bu)2, disproportionation of the Lewis acid results in the formation of a triisobutylaluminium fragment, Al(i-Bu)3, which coordinates to the exocyclic carbonyl O atom of the zirconafuranone ring. Single-crystal X-ray diffraction reveals that the zirconafuranone ring remains intact with coordination of the aluminium to the exocyclic O atom. One of the i-butyl groups is disordered over two sets of sites, with an occupancy ratio of 0.731 (3):0.269 (3).
Description
Keywords
crystal structure, triisobutylaluminium, zirconium metallocene, zwitterionic enolate complex
Citation
Burlakov, V. V., Bogdanov, V. S., Arndt, P., Spannenberg, A., Rosenthal, U., Beweries, T., & Shur, V. B. (2018). Synthesis and crystallographic characterization of [2,2-bis(η5-pentamethylcyclopentadienyl)-3,4-bis(trimethylsilyl)-2-zirconafuran-5-one-κO5]triisobutylaluminium. 74(4). https://doi.org//10.1107/s2056989018004759
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License
CC BY 2.0 UK