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|---|---|---|---|---|
| Lamac et al 2009, 1-Dimethylsilyl-2-phenyl-3-g5-tetramethylcyclopentadienyl.pdf | 405,84 kB | Adobe PDF | View/Open |
| Title: | [1-Dimethylsilyl-2-phenyl-3-(η5-tetramethylcyclopentadienyl) prop-1-en-1-ylκC1](n5-pentamethylcyclopentadienyl)- titanium(III) |
| Authors: | Lamač, M.; Spannenberg, A.; Arndt, P.; Rosenthal, U. |
| Publishers version: | https://doi.org/10.1107/S1600536809044845 |
| URI: | https://doi.org/10.34657/4052 https://oa.tib.eu/renate/handle/123456789/5423 |
| Issue Date: | 2009 |
| Published in: | Acta Crystallographica Section E: Structure Reports Online 65 (2009), 11 |
| Journal: | Acta Crystallographica Section E: Structure Reports Online |
| Volume: | 65 |
| Issue: | 11 |
| Publisher: | Chester : International Union of Crystallography |
| Abstract: | The title compound, [Ti(C10H15)(C20H 26Si)], was obtained from the reaction of [Ti{5: 1-C5Me4(CH2)}(5-C 5Me5)] with the alkynylsilane PhC2SiMe 2H. The complex crystallizes with two independent mol-ecules in the asymmetric unit, which differ in the conformation of the propenyl unit, resulting in their having opposite helicity. No inter-molecular inter-actions or inter-actions involving the Si- H bond are present. The observed geometrical parameters are unexceptional compared to known structures of the same type. |
| Keywords: | Crystal structure; Chemistry; Crystallography |
| Type: | article; Text |
| Publishing status: | publishedVersion |
| DDC: | 540 |
| License: | CC BY 4.0 Unported |
| Link to license: | https://creativecommons.org/licenses/by/4.0/ |
| Appears in Collections: | Chemie |
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Lamač, M., A. Spannenberg, P. Arndt and U. Rosenthal, 2009. [1-Dimethylsilyl-2-phenyl-3-(η5-tetramethylcyclopentadienyl) prop-1-en-1-ylκC1](n5-pentamethylcyclopentadienyl)- titanium(III). 2009. Chester : International Union of Crystallography
Lamač, M., Spannenberg, A., Arndt, P. and Rosenthal, U. (2009) “[1-Dimethylsilyl-2-phenyl-3-(η5-tetramethylcyclopentadienyl) prop-1-en-1-ylκC1](n5-pentamethylcyclopentadienyl)- titanium(III).” Chester : International Union of Crystallography. doi: https://doi.org/10.1107/S1600536809044845.
Lamač M, Spannenberg A, Arndt P, Rosenthal U. [1-Dimethylsilyl-2-phenyl-3-(η5-tetramethylcyclopentadienyl) prop-1-en-1-ylκC1](n5-pentamethylcyclopentadienyl)- titanium(III). Vol. 65. Chester : International Union of Crystallography; 2009.
Lamač, M., Spannenberg, A., Arndt, P., & Rosenthal, U. (2009). [1-Dimethylsilyl-2-phenyl-3-(η5-tetramethylcyclopentadienyl) prop-1-en-1-ylκC1](n5-pentamethylcyclopentadienyl)- titanium(III) (Version publishedVersion, Vol. 65). Version publishedVersion, Vol. 65. Chester : International Union of Crystallography. https://doi.org/https://doi.org/10.1107/S1600536809044845
Lamač M, Spannenberg A, Arndt P, Rosenthal U. [1-Dimethylsilyl-2-phenyl-3-(η5-tetramethylcyclopentadienyl) prop-1-en-1-ylκC1](n5-pentamethylcyclopentadienyl)- titanium(III). 2009;65(11). doi:https://doi.org/10.1107/S1600536809044845
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