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Title: | 1-Butyl-3-methylimidazolium tribromido(triphenylphosphane-κP)nickelate(II) butan-1-ol hemisolvate |
Authors: | Peppel, T.; Köckerling, M. |
Publishers version: | https://doi.org/10.1107/S241431462100818X |
URI: | https://oa.tib.eu/renate/handle/123456789/8496 https://doi.org/10.34657/7534 |
Issue Date: | 2021 |
Published in: | IUCrData 6 (2021) |
Journal: | IUCrData |
Volume: | 6 |
Page Start: | x210818 |
Publisher: | Chester : IUCr |
Abstract: | The solvated title salt, (C8H15N2)[NiBr3(P(C6H5)3)]·0.5C4H10O, was obtained in the form of single crystals directly from the reaction mixture. The molecular structure consists of separated 1-butyl-3-methylimidazolium cations, tribromido(triphenylphosphane)nickelate(II) anions and half a solvent molecule of 1-butanol, all connected via multiple hydrogen contacts to form a three-dimensional network. The co-crystallized 1-butanol molecule is disordered and adopts two orientations. The central C—C bonds of both orientations are located on an inversion centre (Wyckoff site 2b of space group P21/n). Thereby, each orientation has again two orientations with the OH group being located either on one or the other side of the C4 alkyl chain. The dried solvent-free compound exhibits a relatively low melting point (m.p. = 412 K). |
Keywords: | crystal structure; nickel; coordination compound; ionic liquid |
Type: | article; Text |
Publishing status: | publishedVersion |
DDC: | 530 |
License: | CC BY 4.0 Unported |
Link to license: | https://creativecommons.org/licenses/by/4.0/ |
Appears in Collections: | Chemie Physik |
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Peppel, T. and M. Köckerling, 2021. 1-Butyl-3-methylimidazolium tribromido(triphenylphosphane-κP)nickelate(II) butan-1-ol hemisolvate. 2021. Chester : IUCr
Peppel, T. and Köckerling, M. (2021) “1-Butyl-3-methylimidazolium tribromido(triphenylphosphane-κP)nickelate(II) butan-1-ol hemisolvate.” Chester : IUCr. doi: https://doi.org/10.1107/S241431462100818X.
Peppel T, Köckerling M. 1-Butyl-3-methylimidazolium tribromido(triphenylphosphane-κP)nickelate(II) butan-1-ol hemisolvate. Vol. 6. Chester : IUCr; 2021.
Peppel, T., & Köckerling, M. (2021). 1-Butyl-3-methylimidazolium tribromido(triphenylphosphane-κP)nickelate(II) butan-1-ol hemisolvate (Version publishedVersion, Vol. 6). Version publishedVersion, Vol. 6. Chester : IUCr. https://doi.org/https://doi.org/10.1107/S241431462100818X
Peppel T, Köckerling M. 1-Butyl-3-methylimidazolium tribromido(triphenylphosphane-κP)nickelate(II) butan-1-ol hemisolvate. 2021;6. doi:https://doi.org/10.1107/S241431462100818X
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