Determination of side products in the photocatalytic generation of hydrogen with copper photosensitizers by resonance Raman spectroelectrochemistry
Loading...
Date
2016
Volume
6
Issue
107
Journal
RSC Advances : an international journal to further the chemical sciences
Series Titel
Book Title
Publisher
London : RSC Publishing
Link to publishers version
Abstract
A combination of UV-Vis and resonance Raman spectroscopy in conjunction with electrochemistry is employed to reveal the nature of a side product formed when using heteroleptic Cu(I)-photosensitizers [(P^P)Cu(N^N)]+ for photocatalytic hydrogen generation. It is shown that homoleptic [Cu(N^N)2]+ complexes are formed under oxidative conditions confirming a proposed deactivation pathway.
Description
Keywords
Citation
Zhang, Y., Heberle, M., Wächtler, M., Karnahl, M., & Dietzek, B. (2016). Determination of side products in the photocatalytic generation of hydrogen with copper photosensitizers by resonance Raman spectroelectrochemistry (London : RSC Publishing). London : RSC Publishing. https://doi.org//10.1039/c6ra21469j
Collections
License
CC BY 3.0 Unported